Comparative analysis of luminescence Property of Tb3+and Er3+Activated Calcium Silicate Phosphor

Authors

  • Verma S Dept. of Electrical Engineering, Shri Shankracharya Group of Instituionns-Junwani, Bhilai (C.G.), India
  • Mishra A Dept. of Electrical Engineering, Bhilai Institute of Technology-Durg(C.G.), India
  • Bhuie M Dept. of Applied Physics, Shankracharya Group of Instituionns-Junwani, Bhilai (C.G.), India
  • Singh NK Dept. of Applied Physics, Krishna College of Engineering and Technology,Junwani, Bhilai (C.G.), India

DOI:

https://doi.org/10.26438/ijcse/v6i10.108114

Keywords:

X-ray diffract meter (XRD), scanning electron microscopy (SEM), energy dispersive x-ray spectroscopy, (EDX), photoluminescence (PL) and thermo luminescence (TL)

Abstract

The silicates of calcium are known for their thermal stability, high temperature strength, low thermal expansion, cheep residence and chemical inertness. Silicate phosphors are used for a fluorescent, a cathode-ray tube, a luminous body, a vacuum ultraviolet excitation light emitting element etc. Calcium Silicate acquires a higher luminous efficiency when it is doped with rare earth activated ions. In present work the silicate is prepared by combustion method at initiating temperature of 700-8000 C, using urea as a fuel and activated by Er3+ and Tb3+. The prepared CaSiO3:Er3+and CaSiO3:Tb3+ phosphor was characterized by X-ray diffract meter (XRD), scanning electron microscopy (SEM), energy dispersive x-ray spectroscopy (EDX), photoluminescence (PL) and thermo luminescence (TL). The chemical composition of the sintered phosphor was confirmed by EDX spectra, The PL spectra indicate that both phosphor exhibit bright green emission and with excellent colour stability. The PL broadness were typically observed in the range of 650-680 nm. The detail analysis of result it is observed the both compositions are promising green emitting phosphor for white light emitting diode (LED) application.

References

[1] K. S. Hong, R. S. Meltzer, B. Bihari, D. K. Williams, and B. M.Tissue, J. Lumin. 234, 76 (1998).

[2] R. N. Bhargara, D. Gallaghar, X. Hong, and A. Nurmikko, Phys. Rev. Lett. 72, 416 (1994).

[3] Haiyan Jiao and Yuhua Wang, “Ca2Al2SiO7: Ce3+, Tb3+ A White–Light Phosphor Suitable for White–Light-Emitting Diodes” Journal of the Electrochemical Society, 156 (5) J117-J120 (2009).

[4] CAI Jinjun, PAN Huanhuan and WANG Yi, “Luminescence properties of red-emitting Ca2Al2SiO7:Eu3+ nanoparticles pre- pared by sol-gel method” RARE METALS Vol. 30, No. 4, p. 374, 2011.

[5] G.J. Talwar, C.P. Joshi, S.V. Moharil Ã, S.M. Dhopte, “Combustion synthesis of Sr3MgSi2O8:Eu2+and Sr2MgSi2O7:Eu2+phosphors” Journal of Luminescence 129 1239–1241, (2009).

[6] Haoyi Wu, Yihua Hu, Guifang Ju, Li Chen, Xiaojuan Wang, Zhongfu Yang “Photoluminescence and thermo-luminescence of Ce3+ and Eu2+ in Ca2Al2SiO7 matrix” Journal of Luminescence 131, 2441–2445 (2011).

[7] E.C.S.H.D.E. Harrison, N.T. McLamed, A new family of self-activated phosphors, J. Electrochem. Soc. 110 (1963) 23.

[8] J.E.P.-H. Ping Li, I. Wei Chen, X-ray-absorption studies of zirconia polymorphs. III. Static distortion and thermal distortion, Physic Rev. B 48 (1993) 10082.

[9] F.F. Lange, Transformation toughening, J. Mater. Sci. 17 (1982) 255e263.

[10] C. Ming, F. Song, F. Wang, S. An, Y. Cai, X. Ren, et al., Luminescent characters ofEr 3 þ/Yb 3 þ co-doped ZrO 2 e Al 2 O 3 phosphors, J. Lumin 168 (2015) 59e61.

[11] R.I. Merino, J.A. Pardo, J.I. Pe~na, V.M. Orera, Microstructure-size dependence of the 1.520 mm Er[sup 3þ] luminescence lifetime in Al[sub 2]O[sub 3]eZrO[sub 2] eutectic melt growth composites, Appl. Phys. Lett. 80 (2002) 589.

[12] T. Rivera, R. Sosa, J. Azorín, J. Zarate, A. Ceja, Synthesis and luminescent characterization of sol-gel derived zirconia-alumina, Radiat. Meas. 45 (2010) 465e467.

[13] Haiyan Jiao and Yuhua Wang, “Ca2Al2SiO7: Ce3+, Tb3+ A White–Light Phosphor Suitable for White–Light-Emitting Diodes” Journal of the Electrochemical Society, 156 (5) J117-J120 (2009).

[14] R. Chen, Y. Krish., Analysis of thermally stimulated process, Pergamon, New York (1981).

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Published

2025-11-17
CITATION
DOI: 10.26438/ijcse/v6i10.108114
Published: 2025-11-17

How to Cite

[1]
S. Verma, A. Mishra, M. Bhuie, and N. K. Singh, “Comparative analysis of luminescence Property of Tb3+and Er3+Activated Calcium Silicate Phosphor”, Int. J. Comp. Sci. Eng., vol. 6, no. 10, pp. 108–114, Nov. 2025.

Issue

Vol. 6 No. 10 (2018): IJCSE October Edition

Section

Research Article

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